Which condition leads to corrosion in boiler systems?

Corrosion in boiler systems is significantly influenced by the water chemistry present within the system, and low alkaline water combined with the presence of free oxygen is a critical condition that fosters corrosion.

When the water in the boiler system is low in alkalinity, it means that it has a reduced capacity to neutralize acids that can form, which can lead to a decrease in pH levels. This acidic environment can accelerate the corrosion process. Additionally, the presence of free oxygen exacerbates the situation because oxygen can react with metal components in the boiler, leading to oxidative corrosion. The combination of low alkaline conditions and free oxygen creates an environment where the corrosive potential is maximized, leading to deterioration of the metal surfaces.

In contrast, high alkaline levels or high total dissolved solids (TDS) might contribute to other issues, such as scaling or carryover, but they do not primarily lead to corrosion in the same way that the specific combination of low alkalinity and free oxygen does. Excess heat retention may also affect the performance and efficiency of a boiler but is not directly tied to the corrosion process in the same manner as the conditions mentioned.